H-transfer rates in ion-neutral complexes versus those in intact aliphatic ions

The relative rates of H-transfer between partners in ion-neutral complexes were compared with those in intramolecular rearrangements using results of first differential photoionization mass spectrometry measurements. Complex-mediated H-transfers are inferred to have rates of the same order as those for intramolecular hydrogen rearrangements, suggesting a similar range of motion of the reactive sites in both types of reactions. It is also concluded that at their fastest H-transfers take place between the partners in ion-neutral complexes within at most the time of several rotations of the partners in the complexes. Copyright 1999 John Wiley & Sons, Ltd.     

Self-shrinkers for the mean curvature flow in arbitrary codimension

In this paper, we generalize Colding–Minicozzi’s recent results about codimension-1 self-shrinkers for the mean curvature flow to higher codimension. In particular, we prove that the sphere ${bf S}^{n}(\sqrt{2n})$ is the only complete embedded connected $F$ -stable self-shrinker in $\mathbf{R}^{n+k}$ with $\mathbf{H}\ne 0$ , polynomial volume growth, flat normal bundle and bounded geometry. We also discuss some properties of symplectic self-shrinkers, proving that any complete symplectic self-shrinker in $\mathbf{R}^4$ with polynomial volume growth and bounded second fundamental form is a plane. As a corollary, we show that there is no finite time Type I singularity for symplectic mean curvature flow, which has been proved by Chen–Li using different method. We also study Lagrangian self-shrinkers and prove that for Lagrangian mean curvature flow, the blow-up limit of the singularity may be not $F$ -stable.     

Szegö kernel, regular quantizations and spherical CR-structures

We compute the Szegö kernel of the unit circle bundle of a negative line bundle dual to a regular quantum line bundle over a compact Kähler manifold. As a corollary we provide an infinite family of smoothly bounded strictly pseudoconvex domains on complex manifolds (disk bundles over homogeneous Hodge manifolds) for which the log-terms in the Fefferman expansion of the Szegö kernel vanish and which are not locally CR-equivalent to the sphere. We also give a proof of the fact that, for homogeneous Hodge manifolds, the existence of a locally spherical CR-structure on the unit circle bundle alone implies that the manifold is biholomorphic to a projective space. Our results generalize those obtained by Engli? (Math Z 264(4):901–912, 2010) for Hermitian symmetric spaces of compact type.     

Disentangling the effects of phonation and articulation: Hemispheric asymmetries in the auditory N1m response of the human brain

Background  

The cortical activity underlying the perception of vowel identity has typically been addressed by manipulating the first and second formant frequency (F1 & F2) of the speech stimuli. These two values, originating from articulation, are already sufficient for the phonetic characterization of vowel category. In the present study, we investigated how the spectral cues caused by articulation are reflected in cortical speech processing when combined with phonation, the other major part of speech production manifested as the fundamental frequency (F0) and its harmonic integer multiples. To study the combined effects of articulation and phonation we presented vowels with either high (/a/) or low (/u/) formant frequencies which were driven by three different types of excitation: a natural periodic pulseform reflecting the vibration of the vocal folds, an aperiodic noise excitation, or a tonal waveform. The auditory N1m response was recorded with whole-head magnetoencephalography (MEG) from ten human subjects in order to resolve whether brain events reflecting articulation and phonation are specific to the left or right hemisphere of the human brain.